Skip to main navigation menu Skip to main content Skip to site footer

Performance of Soil-Based Controlled Low-Strength Material Prepared with Alkali-Activated Slag and Coal Bottom Ash

Abstract

The utilisation of excavated soil with high moisture and high viscosity faces challenges such as complex dehydration processes and difficult material dispersion. Controlled Low-Strength Material (CLSM) provides a feasible pathway for its dehydration-free resource utilisation. To enhance sustainability, alkali-activated materials can replace Portland cement as the binder in CLSM. However, the influences of activator concentration on CLSM performance remain unclear, and the dispersibility of high-viscosity soil needs further improvement. Therefore, this study develops a novel CLSM using high-viscosity excavated soil and alkali-activated slag, with coal bottom ash (CBA) introduced to improve its dispersibility. Through flowability, setting time, and compressive strength tests, the influences of binder content, alkaline dosage, silicate modulus, soil-to-aggregate ratio, and wet-dry cycles on CLSM performance are systematically investigated, followed by hydration heat and thermogravimetric analyses to reveal the underlying mechanisms. The results demonstrate that increasing the binder content promotes hydration and enhances the mechanical properties of CLSM. CBA can effectively improve flowability but has limited effects on hydration and strength enhancement. Increasing the alkaline dosage accelerates early hydration and increases 7-day compressive strength but may retard later-stage strength development. Reducing the silicate modulus is beneficial to early hydration and performance, whereas a high modulus presents higher later-stage compressive strength. Wet-dry cycles exert dual effects on CLSM through promoting hydration and inducing internal crack propagation, ultimately resulting in strength degradation under wet-dry cycles. This paper provides a theoretical basis and technical reference for the efficient and low-carbon resource utilisation of high-viscosity excavated soil as filling material.

Keywords

CLSM, Excavated soil, Coal bottom ash, Alkaline dosage, Silicate modulus, Wet-dry cycles

PDF

Author Biography

Jiaqi Wu

.


References

  1. Wang, B., Xiao, J., Zheng, Z., Gan, W., Shen, J., & Wang, J. (2025). Assessment of construction spoil generation: A case study in China. Journal of Cleaner Production, 532, 146879. https://doi.org/10.1016/j.jclepro.2025.146879
  2. Wang, H., Zhang, N., Duan, H., & Dong, L. (2024). Pathways to sound management of excavated soil and rock: A case study in Shenzhen. Journal of Cleaner Production, 458, 142383. https://doi.org/10.1016/j.jclepro.2024.142383
  3. Cristóbal, J., Foster, G., Caro, D., Yunta, F., Manfredi, S., & Tonini, D. (2024). Management of excavated soil and dredging spoil waste from construction and demolition within the EU: Practices, impacts and perspectives. Science of The Total Environment, 944, 173859. https://doi.org/10.1016/j.scitotenv.2024.173859
  4. Zhu, Y., Liu, D., Fang, G., Wang, H., & Cheng, D. (2022). Utilization of excavated loess and gravel soil in controlled low strength material: Laboratory and field tests. Construction and Building Materials, 360, 129604. https://doi.org/10.1016/j.conbuildmat.2022.129604
  5. Luo, W., Liu, S., Hu, Y., Hu, D., Kow, K. W., Pang, C., & Li, B. (2022). Sustainable reuse of excavated soil and recycled concrete aggregate in manufacturing concrete blocks. Construction and Building Materials, 342, 127917. https://doi.org/10.1016/j.conbuildmat.2022.127917
  6. Luo, W., Liu, S., Jiang, Y., Guan, X., Hu, Y., Hu, D., & Li, B. (2021). Utilisation of dewatered extracted soil in concrete blocks produced with Portland cement or alkali-activated slag: Engineering properties and sustainability. Case Studies in Construction Materials, 15, e00760.https://doi.org/10.1016/j.cscm.2021.e00760
  7. Liu, S., Zhang, W., Xu, M., Wang, F., Hu, Y., & Li, B. (2024). Development of cold-bond artificial aggregate with excavated soil and alkali-activated slag. Case Studies in Construction Materials, 21, e03451. https://doi.org/10.1016/j.cscm.2024.e03451
  8. Yan, N., Li, G., Qin, F., Qiao, X., Lu, B., Liang, N., & Zhao, S. (2025). Study on the deformation characteristics of diaphragm walls in deep excavations within the Ningbo soft soil region. Scientific Reports, 15(1), 15036. https://doi.org/10.1038/s41598-025-95878-y
  9. Mahmoud, A., Olivier, J., Vaxelaire, J., & Hoadley, A. F. (2012). Advances in mechanical dewatering of wastewater sludge treatment. In Wastewater reuse and management (pp. 253-303). Dordrecht: Springer Netherlands. https://doi.org/10.1007/978-94-007-4942-9_9
  10. Aziz, M., Sheikh, F. N., Qureshi, M. U., Rasool, A. M., & Irfan, M. (2021). Experimental study on endurance performance of lime and cement-treated cohesive soil. KSCE Journal of Civil Engineering, 25(9), 3306-3318. https://doi.org/10.1007/s12205-021-2154-7
  11. Kim, Y. S., Do, T. M., Kim, H. K., & Kang, G. (2016). Utilization of excavated soil in coal ash-based controlled low strength material (CLSM). Construction and Building Materials, 124, 598-605. https://doi.org/10.1016/j.conbuildmat.2016.07.053
  12. DeLeo, P. C., Baveye, P., & Ghiorse, W. C. (1997). Use of confocal laser scanning microscopy on soil thin-sections for improved characterization of microbial growth in unconsolidated soils and aquifer materials. Journal of Microbiological Methods, 30(3), 193-203. https://doi.org/10.1016/S0167-7012(97)00065-1
  13. Kaliyavaradhan, S. K., Ling, T. C., Guo, M. Z., & Mo, K. H. (2019). Waste resources recycling in controlled low-strength material (CLSM): A critical review on plastic properties. Journal of Environmental Management, 241, 383-396. https://doi.org/10.1016/j.jenvman.2019.03.017
  14. Sheen, Y. N., Zhang, L. H., & Le, D. H. (2013). Engineering properties of soil-based controlled low-strength materials as slag partially substitutes to Portland cement. Construction and Building Materials, 48, 822-829. https://doi.org/10.1016/j.conbuildmat.2013.07.046
  15. He, Z., Zhu, X., Wang, J., Mu, M., & Wang, Y. (2019). Comparison of CO2 emissions from OPC and recycled cement production. Construction and Building Materials, 211, 965-973. https://doi.org/10.1016/j.conbuildmat.2019.03.289
  16. Roy, D. M. (1999). Alkali-activated cements opportunities and challenges. Cement and Concrete Research, 29(2), 249-254. https://doi.org/10.1016/S0008-8846(98)00093-3
  17. Provis, J. L. (2018). Alkali-activated materials. Cement and Concrete Research, 114, 40-48. https://doi.org/10.1016/j.cemconres.2017.02.009
  18. Thomas, R. J., Ye, H., Radlinska, A., & Peethamparan, S. (2016). Alkali-activated slag cement concrete. Concrete International, 38(1), 33-38. https://doi.org/10.14359/51688712
  19. Yang, K. H., Song, J. K., & Song, K. I. (2013). Assessment of CO2 reduction of alkali-activated concrete. Journal of Cleaner Production, 39, 265-272. https://doi.org/10.1016/j.jclepro.2012.08.001
  20. Tan, Y., He, Y., Cui, X., & Liu, L. (2024). The influence of different water glass moduli on the chemical corrosion resistance of alkali-activated porous concrete. Construction and Building Materials, 415, 134971.
  21. https://doi.org/10.1016/j.conbuildmat.2024.134971
  22. Lee, N. K., Kim, H. K., Park, I. S., & Lee, H. K. (2013). Alkali-activated, cementless, controlled low-strength materials (CLSM) utilizing industrial by-products. Construction and Building Materials, 49, 738-746. https://doi.org/10.1016/j.conbuildmat.2013.09.002
  23. Fang, S., Lam, E. S. S., Li, B., & Wu, B. (2020). Effect of alkali contents, moduli and curing time on engineering properties of alkali activated slag. Construction and Building Materials, 249, 118799. https://doi.org/10.1016/j.conbuildmat.2020.118799
  24. Lang, L., Chen, B., & Chen, B. (2021). Strength evolutions of varying water content-dredged sludge stabilized with alkali-activated ground granulated blast-furnace slag. Construction and Building Materials, 275, 122111. https://doi.org/10.1016/j.conbuildmat.2020.122111
  25. Wan, X., Ding, J., Jiao, N., Zhang, S., Wang, J., & Guo, C. (2023). Preparing controlled low strength materials (CLSM) using excavated waste soils with polycarboxylate superplasticizer. Environmental Earth Sciences, 82(9), 214. https://doi.org/10.1007/s12665-023-10884-5
  26. Khadka, S. D., Okuyucu, O., Jayawickrama, P. W., & Senadheera, S. (2023). Controlled low strength materials (CLSM) activated with alkaline solution: Flowability, setting time and microstructural characteristics. Case Studies in Construction Materials, 18, e01892. https://doi.org/10.1016/j.cscm.2023.e01892
  27. Shin, Y., Jang, J. G., Choi, J., Jun, G., Park, C., Kim, G. M., & Yang, B. (2023). Utilization of artificial interior stone sludge as fine aggregate in controlled low-strength material (CLSM). Journal of Building Engineering, 71, 106441. https://doi.org/10.1016/j.jobe.2023.106441
  28. Ali, H. A., Zhang, B., Xiao, C., Zhao, B., Xuan, D., & Poon, C. S. (2022). Valorization of fine recycled C&D aggregate and incinerator bottom ash for the preparation of controlled low-strength material (CLSM). Cleaner Waste Systems, 3, 100061. https://doi.org/10.1016/j.clwas.2022.100061
  29. Singh, M. (2018). Coal bottom ash. In Waste and supplementary cementitious materials in concrete (pp. 3-50). Woodhead Publishing. https://doi.org/10.1016/B978-0-08-102156-9.00001-8
  30. Lakhiar, M. T., Bai, Y., Wong, L. S., Paul, S. C., Anggraini, V., & Kong, S. Y. (2022). Mechanical and durability properties of epoxy mortar incorporating coal bottom ash as filler. Construction and Building Materials, 315, 125677. https://doi.org/10.1016/j.conbuildmat.2021.125677
  31. Wu, J. Q., Li, B., Chen, Y. T., & Ghiassi, B. (2023). Investigation on the roles of glass sand in sustainable engineered geopolymer composites. Construction and Building Materials, 363, 129576. https://doi.org/10.1016/j.conbuildmat.2022.129576
  32. Guan, X., Luo, W., Liu, S., Hernandez, A. G., Do, H., & Li, B. (2023). Ultra-high early strength fly ash-based geopolymer paste cured by microwave radiation. Developments in the Built Environment, 14, 100139. https://doi.org/10.1016/j.dibe.2023.100139
  33. ASTM D6103-17; Standard Test Method for Flow Consistency of Controlled Low Strength Material (CLSM). ASTM International: West Conshohocken, PA, USA, 2017.
  34. GB/T 1346-2024: Test methods for water requirement of standard consistency, setting time and soundness of the Portland cement. Standardization Administration and General Administration of Quality Supervision, Inspection and Quar-antine of China, Beijing, China, 2011.
  35. ASTM, D4832. Standard Test Method for Preparation and Testing of Controlled Low Strength Material (CLSM) Test Cylinders. ASTM International: West Conshohocken, PA, USA, 2002.
  36. ASTM D559/D559M-15. Standard Test Methods for Wetting and Drying Compacted Soil-Cement Mixtures. ASTM International: West Conshohocken, PA, USA, 2023.
  37. Rafeet, A., Vinai, R., Soutsos, M., & Sha, W. (2019). Effects of slag substitution on physical and mechanical properties of fly ash-based alkali activated binders (AABs). Cement and Concrete Research, 122, 118-135. https://doi.org/10.1016/j.cemconres.2019.05.003
  38. Lakhiar, M. T., Bai, Y., Wong, L. S., Paul, S. C., Anggraini, V., & Kong, S. Y. (2022). Mechanical and durability properties of epoxy mortar incorporating coal bottom ash as filler. Construction and Building Materials, 315, 125677. https://doi.org/10.1016/j.conbuildmat.2021.125677
  39. Nedunuri, A. S. S. S., & Muhammad, S. (2021). Fundamental understanding of the setting behaviour of the alkali activated binders based on ground granulated blast furnace slag and fly ash. Construction and Building Materials, 291, 123243. https://doi.org/10.1016/j.conbuildmat.2021.123243
  40. Chang, J. J. (2003). A study on the setting characteristics of sodium silicate-activated slag pastes. Cement and Concrete Research, 33(7), 1005-1011. https://doi.org/10.1016/S0008-8846(02)01096-7
  41. Kaze, C. R., Djobo, J. N. Y., Nana, A., Tchakoute, H. K., Kamseu, E., Melo, U. C., ... & Rahier, H. (2018). Effect of silicate modulus on the setting, mechanical strength and microstructure of iron-rich aluminosilicate (laterite) based-geopolymer cured at room temperature. Ceramics International, 44(17), 21442-21450. https://doi.org/10.1016/j.ceramint.2018.08.205
  42. Ouyang, X., Ma, Y., Liu, Z., Liang, J., & Ye, G. (2019). Effect of the sodium silicate modulus and slag content on fresh and hardened properties of alkali-activated fly ash/slag. Minerals, 10(1), 15. https://doi.org/10.3390/min10010015
  43. Qi, W., Duan, G., Han, Y., Zhao, Q., Huang, Y., Zhu, W., ... & Zhang, J. (2024). Comparison of mechanical properties and microstructure of GGBS-based cementitious materials activated by different combined alkaline wastes. Construction and Building Materials, 422, 135784. https://doi.org/10.1016/j.conbuildmat.2024.135784
  44. Huang, Y., Gong, A., Jin, Z., Peng, Y., Shao, S., & Yong, K. (2025). Synergistic Effects of Alkali Activator Dosage on Carbonation Resistance and Microstructural Evolution of Recycled Concrete: Insights from Fractal Analysis and Optimal Threshold Identification. Buildings, 15(10), 1742. https://doi.org/10.3390/buildings15101742
  45. Gebregziabiher, B. S., Thomas, R. J., & Peethamparan, S. (2016). Temperature and activator effect on early-age reaction kinetics of alkali-activated slag binders. Construction and Building Materials, 113, 783-793. https://doi.org/10.1016/j.conbuildmat.2016.03.098
  46. Adewumi, A. A., Mohd Ariffin, M. A., Maslehuddin, M., Yusuf, M. O., Ismail, M., & Al-Sodani, K. A. A. (2021). Influence of silica modulus and curing temperature on the strength of alkali-activated volcanic ash and limestone powder mortar. Materials, 14(18), 5204. https://doi.org/10.3390/ma14185204
  47. Hu, W., Li, K., Yin, W., Zhang, H., Xue, Y., Han, Y., & Liu, P. (2024). Effects of wetting–drying cycles on the macro and micro properties of the cement-stabilized soil with curing agent. Buildings, 14(6), 1716. https://doi.org/10.3390/buildings14061716
  48. He, J., Bai, W., Zheng, W., He, J., & Sang, G. (2021). Influence of hydrated lime on mechanical and shrinkage properties of alkali-activated slag cement. Construction and Building Materials, 289, 123201. https://doi.org/10.1016/j.conbuildmat.2021.123201
  49. Ye, H., & Huang, L. (2020). Shrinkage characteristics of alkali-activated high-volume fly-ash pastes incorporating silica fume. Journal of Materials in Civil Engineering, 32(10), 04020307. https://doi.org/10.1061/(ASCE)MT.1943-5533.0003384
  50. Liu, Y., Feng, S., & Liu, H. (2024). Measurements of drying and wetting gas diffusion coefficients and gas permeability of unsaturated soils using a new flexible-wall device. Journal of Geotechnical and Geoenvironmental Engineering, 150(11), 06024006. https://doi.org/10.1061/JGGEFK.GTENG-12475
  51. Kim, H. K., & Lee, H. K. (2018). Hydration kinetics of high-strength concrete with untreated coal bottom ash for internal curing. Cement and concrete composites, 91, 67-75.https://doi.org/10.1016/j.cemconcomp.2018.04.017
  52. Cai, G. H., Zhou, Y. F., Li, J. S., Han, L. J., & Poon, C. S. (2022). Deep insight into mechanical behavior and microstructure mechanism of quicklime-activated ground granulated blast-furnace slag pastes. Cement and Concrete Composites, 134, 104767. https://doi.org/10.1016/j.cemconcomp.2022.104767
  53. Kim, H. K., & Lee, H. K. (2018). Hydration kinetics of high-strength concrete with untreated coal bottom ash for internal curing. Cement and Concrete Composites, 91, 67-75. https://doi.org/10.1016/j.cemconcomp.2018.04.017
  54. Tiu, E. S. K., Raman, S. N., Kong, D., Sofi, M., & Geng, G. (2025). Correlating the reactivity and strength development of coal bottom ash and coal fly ash in cementitious system. Construction and Building Materials, 466, 140318. https://doi.org/10.1016/j.conbuildmat.2025.140318
  55. Zhang, M., Zunino, F., Yang, L., Wang, F., & Scrivener, K. (2023). Understanding the negative effects of alkalis on long-term strength of Portland cement. Cement and Concrete Research, 174, 107348. https://doi.org/10.1016/j.cemconres.2023.107348
  56. Shi, Z., Shi, C., Wan, S., & Zhang, Z. (2018). Effects of alkali dosage and silicate modulus on alkali-silica reaction in alkali-activated slag mortars. Cement and Concrete Research, 111, 104-115. https://doi.org/10.1016/j.cemconres.2018.06.005